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  • ISSN[Online] : 2643-9875  ||  ISSN[Print] : 2643-9840

Volume 05 Issue 07 July 2022

Removal of Remazol Brilliant Blue R (RBBR) by Absorbsion on Zeolit Cuo Catalyst
1Indra Gunawan, 2Deswita, 3Yoki Yulizar, 4Kandhi Puspa Melati
1,2Research Center for Radiation Detection and Nuclear Analysis Technology, National Research and Innovation Agency, Kawasan Puspiptek Serpong, Tangerang, Indonesia
3,4Department of Chemistry, University ogf Indonesia Kampus Baru UI, Depok, Indonesia
DOI : https://doi.org/10.47191/ijmra/v5-i7-17

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ABSTRACT:

The pollution caused by dyestuffs has been a serious environmental problem for years. Within the overall category of dyestuffs, Remazol Brilliant Blue R (RBBR) is an anthraquinone dye used in textile industries. This paper concerns the study of the different experimental parameters which affect the decolorization efficiency of the RBBR mixture. Thermal degradation is done by carried out with 4 mL of 10 ppm RBBR solution into the reaction flask. Added a number of H2O2 and CuO zeolite catalyst. The reactor was heated in oil bath glycerin and stirred for 90 minutes. The optimum catalyst weight was obtained at 100 mg, which was able to decrease the reaction time 50 minutes compared to the reaction without catalyst. The percentage of dye removal on this catalyst loading was 96.26%. The micro pores of CuO zeolite is about 20 nm, which shows formation of nanoCuO particles in zeolite structure. This structural feature may be important since it increases the total surface area. The diffusion into such pores can explain the absorption capacity.

KEYWORDS:

Dyestuffs pollutant, Absorption capacity, Remazol Brilliant Blue R, Zeolite, CuO, Catalyst

REFERENCES

1) Ates, A., and Hardacre, C., 2012, The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments, J. Colloid Interface Sci., 372 (1), 130–140.

2) Abelló, S., Hevia, M. A. G., Santiago, M., and Pérez-Ramírez, J., 2010, DRIFTS study of the catalytic N2O reduction by SO2 on FeZSM-5, Catal. Commun., 11 (13), 1058–1062.

3) Kuhn, J., Motegh, M., Gross, J., and Kapteijn, F., 2009, Detemplation of [B]MFI zeolite crystals by ozonication, Microporous Mesoporous Mater., 120 (1–2), 35–38.

4) Ji, Y. J., Zhang, B., Xu, L., Wu, H., Peng, H., Chen, L., Liu, Y., and Wu, P., 2011, Core/shell-structured Al-MWW@B-MWW zeolites for shape-selective toluene disproportionation to para-xylene, J. Catal., 283 (2), 168–177.

5) Fan, W., Wu, C., Zhao, C., Yu, T., and Zhang, Y., 2007, Photocatalytic degradation of Acid Blue 62 over CuO-SnO2 nanocomposite photocatalyst under simulated sunlight, J. Environ. Sci. 19(2007) 1141–1145 Photocatalytic, 19, 1141–1145.

6) Melián-Cabrera, I., van Eck, E. R. H., Espinosa, S., Siles-Quesada, S., Falco, L., Kentgens, A. P. M., Kapteijn, F., and Moulijn, J. A., 2017, Tail gas catalyzed N2O decomposition over Fe-beta zeolite. On the promoting role of framework connected AlO6 sites in the vicinity of Fe by controlled dealumination during exchange, Appl. Catal. B Environ.,.

7) Mehrdad, A., Massoumi, B., and Hashemzadeh, R., 2011, Kinetic study of degradation of Rhodamine B in the presence of hydrogen peroxide and some metal oxide, Chem. Eng. J., 168 (3), 1073–1078.

8) Nezamzadeh-Ejhieh, A., and Hushmandrad, S., 2010, Solar photodecolorization of methylene blue by CuO/X zeolite as a heterogeneous catalyst, Appl. Catal. A Gen., 388 (1–2), 149–159.

9) Farbod, M., and Khademalrasool, M., 2011, Synthesis of TiO2 nanoparticles by a combined sol-gel ball milling method and investigation of nanoparticle size effect on their photocatalytic activities, Powder Technol., 214 (3), 344–348.

10) Akyol, A., and Bayramoǧlu, M., 2005, Photocatalytic degradation of Remazol Red F3B using ZnO catalyst, J. Hazard. Mater., 124 (1–3), 241–246.

11) Nezamzadeh-Ejhieh, A., and Karimi-Shamsabadi, M., 2013, Decolorization of a binary azo dyes mixture using CuO incorporated nanozeolite-X as a heterogeneous catalyst and solar irradiation, Chem. Eng. J., 228, 631–641.

12) Nezamzadeh-Ejhieh, A., and Amiri, M., 2013, CuO supported Clinoptilolite towards solar photocatalytic degradation of p-aminophenol, Powder Technol., 235, 279–288.

13) Lu, G., Li, X., Qu, Z., Zhao, Q., Zhao, L., and Chen, G., 2011, Copper-ion exchanged Ti-pillared clays for selective catalytic reduction of NO by propylene, Chem. Eng. J., 168 (3), 1128–1133.

14) Ameta, P., Kumar, A., Ameta, R., and Malkani, R. K., 2010, A comparative study of photocatalytic activity of some coloured semiconducting oxides, Iran. J. Chem. Chem. Eng., 29 (2), 43–48.

15) Niwa, M., Morishita, N., Tamagawa, H., and Katada, N., 2012, HZSM-5 treated with ammonia and water vapor: Characterization and cracking activity, Catal. Today, 198 (1), 12–18.

16) Zhou, Y., Wang, L., Ye, Z., Zhao, M., and Huang, J., 2014, Synthesis of ZnO micro-pompons by soft template-directed wet chemical method and their application in electrochemical biosensors, Electrochim. Acta, 115, 277–282.

17) Kondratenko, E. V., Kondratenko, V. A., Santiago, M., and Pérez-Ramírez, J., 2008, Mechanistic origin of the different activity of Rh-ZSM-5 and Fe-ZSM-5 in N2O decomposition, J. Catal., 256 (2), 248–258.

18) Huang, Q., Xue, X., and Zhou, R., 2010, Decomposition of 1,2-dichloroethane over CeO2 modified USY zeolite catalysts: Effect of acidity and redox property on the catalytic behavior, J. Hazard. Mater., 183 (1–3), 694–700.

19) Wan, X., Yuan, M., Tie, S. L., and Lan, S., 2013, Effects of catalyst characters on the photocatalytic activity and process of NiO nanoparticles in the degradation of methylene blue, Appl. Surf. Sci., 277 (3), 40–46.

20) Jiang, Y., Huang, J., and Hunger, M., 2011, Effect of reactant density inside supercages of zeolite La,Na-Y on the mechanism of the ethylbenzene conversion, Catal. Today, 164 (1), 119–123.

21) Mignani, A., Ballarin, B., Boanini, E., and Cassani, M. C., 2014, Simple one step electrochemical preparation of copper nanostructures, Electrochim. Acta, 115, 537–545.

22) Jae, J., Tompsett, G. A., Foster, A. J., Hammond, K. D., Auerbach, S. M., Lobo, R. F., and Huber, G. W., 2011, Investigation into the shape selectivity of zeolite catalysts for biomass conversion, J. Catal., 279 (2), 257–268.

Volume 05 Issue 07 July 2022

There is an Open Access article, distributed under the term of the Creative Commons Attribution – Non Commercial 4.0 International (CC BY-NC 4.0) (https://creativecommons.org/licenses/by-nc/4.0/), which permits remixing, adapting and building upon the work for non-commercial use, provided the original work is properly cited.


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