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  • ISSN[Online] : 2643-9875  ||  ISSN[Print] : 2643-9840

VOLUME 02 ISSUE 02 NOVEMBER 2019

Evaluation of the Alcalis and Sulfur Cycle in Clinker Kilns
1Javier Alejandro Feijoó Caraballo,2 José A. Fabelo Falcón, 3Iván L. Rodríguez Rico
1Departamento de la Gerencia de Planta. Fábrica de Cementos Cienfuegos, Cuba
2,3Departamento de Ingeniería Química. Facultad de Química y Farmacia. Universidad Central “Marta Abreu” de las Villas, Cuba
Corresponding Author : Javier Alejandro Feijoó Caraballo
Departamento de la Gerencia de Planta. Fábrica de Cementos Cienfuegos, Cuba
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ABSTRACT

In the present work an analysis was made of the formation of crusts or rings in clinker kilns of cement factories in Cuba and Argentina because these formations are one of the most serious problems presented by the kiln areas, which bring with them, stops unnecessary of the entities. With the use of phenomenological models, general parameters were determined, as well as several residence times of the ovens, as appropriate. In addition, several balances were made in a general way and specifically in several scenarios with the Matlab software in function of the different compounds that enter the furnace or that are formed within it, taking sulfur and sodium as main substances of study, in order , to determine several aspects of them, such as: their influence on the formation of the rings, the quantities present in the system, their main reactions, their behavior in normal operating contexts and in conditions of instability, as well as possible solutions for its mitigation and control in kilns. The calculations showed that sulfur and sodium should be managed close to the parameters established by the entities for a good operation of the ovens, thus avoiding unnecessary stops due to ring formation.

KEY-WORDS

Ring; Sulfur; Kiln; Matlab; Reactions

REFERENCES

1. Canales, C., Guía de mejores técnicas disponibles en España de fabricación de cemento., Editorial Centro de Publicaciones Secretaría General Técnica Ministerio de Medio Ambiente, Cataluña., España., 2004, pp. 25-46

2. D.Sullivan, J. (1927) Passage of solid particles through rotary cylindrical kilns. Washington, United States.

3. Fernandez, Y., Obtención del límite de SO3 en la mezcla de materias primas para determinar el uso del Adi3tek en el proceso de fabricación de clinker, Tesis presentada en opción al Grado Científico de Graduado de Nivel Superior en la especialidad de Ingeniería Química en la Universidad de Cienfuegos, Cuba, 2015, pp. 16-18.

4. Levenspiel, O., Ingeniería de las reacciones químicas., Editorial Reverté, S.A., Barcelona, España., 1987, pp. 393-405.

5. Liu, X. Y., & Specht, E. (2006) Mean residence time and hold-up of solids in rotary kilns. China, Chemical Engineering Science.

6. Moreira, Q., Capacitación sobre química del cemento., Publicación especial, Guabairo, Cementos Cienfuegos., Cuba., 2011, pp.2-8.

7. McCabe, W., Harriot, P., Operaciones Unitarias en Ingeniería Química., Editorial McGraw-Hill/interamericana, 1998, pp. 19-20.

8. Rodríguez, P., Análisis SO3 Yacimiento de caliza., Publicación especial, Guabairo, Cementos Cienfuegos., Cuba., 2014, pp. 1-5.

9. Sánchez, N., Influencia del proceso de fabricación y formación de anillos y bolas en los hornos rotatorios en la preparación del cemento portland., Coloquio de química del Cemento., Pacasmayo., Compañía Cementos Norte Pacasmayo S. A., Perú., 2006, pp. 59-63.

10. Santamaría, F. S., (1982), Influencia de los componentes minoritarios en la producción de cemento., Coloquio-Panel sobre, El futuro de los carbones españoles, León, España.

11. Saeman, W. C. (1951) Passage of solids through rotary kilns. Washington, United States.

12. Soria, S., Influencia de los componentes minoritarios en la producción de cemento., memorias de la Conferencia pronunciada en el Coloquio-Panel sobre, El futuro de los carbones españoles, celebrado en León los días 16, 17 y 18 de septiembre del 1982, pp. 67-79.

VOLUME 02 ISSUE 02 NOVEMBER 2019

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